Erasable ink composition for writing on impervious surface

ABSTRACT

An erasable ink composition for writing on an impervious writing surface comprising an organic solvent, a resin, a pigment, and a separating agent which comprises a polyoxyethylene polyoxypropylene monoalkyl ether which is liquid at normal temperatures in an amount of 5-20% by weight, and optionally at least one organic compound selected from the group consisting of a carboxylic acid ester and a polyoxypropylene monoalkyl ether which is liquid at normal temperatures in an amount of 2-10% by weight in conjunction.

FIELD OF THE INVENTION

This invention relates to an erasable ink composition for writing on an impervious writing surface, and more particularly, to an erasable ink composition which contains a separating agent therein to provide writing on an impervious writing surface such as a so-called white board which is readily erasable by wiping lightly with an eraser made of, for example, felt.

BACKGROUND OF THE INVENTION

A variety of erasable ink composition to write on an impervious writing surface to provide writing thereon which is readily erasable by wiping with, for example, an eraser made of felt are already known, as disclosed in, for example, Japanese Patent Application Laid-open No. 63-43981, No. 62-265377 and No. 2-129278. However, these prior erasable ink compositions contain carboxylic acid esters, liquid paraffin, silicone resins or nonionic surfactants as a separating agent therein, and thus it is known that they provide writing which is insufficiently erasable depending upon the material of impervious writing surface. Namely, the prior erasable ink compositions have erasability dependendent on the material of impervious writing surface. It is also known that such an ink composition provides writing which is not readily erasable after long standing. Namely, the prior erasable ink compositions have erasability dependendent on time.

BRIEF SUMMARY OF THE INVENTION

It is an object of the invention to provide an ink composition which provides writing on an impervious writing surface readily erasable irrespective of the material of the surface and after long standing.

According to the invention, there is provided a erasable ink composition for writing on an impervious writing surface comprising an organic solvent, a resin, a pigment, and a separating agent which comprises a polyoxyethylene polyoxypropylene monoalkyl ether which is liquid at normal temperatures in an amount of 5-20% by weight.

DETAILED DESCRIPTION OF THE INVENTION

The ink composition of the invention contains an organic solvent preferably such as an alcohol or a glycol monoalkyl ether. The alcohol is preferably an aliphatic alcohol of 1-4 carbons such as methanol, ethanol, isopropyl alcohol, n-propyl alcohol or butanol. The glycol monoalkyl ether is preferably a monoalkyl ether of glycol of 2-4 carbons such as ethylene glycol monomethyl ether, ethylene glycol monoethyl ether, propylene glycol monomethyl ether or propylene glycol monoethyl ether. These solvents may be used singly or as a mixture.

The ink compositions of the invention contains such an organic solvent in an amount of 40-90% by weight, preferably in an amount of 50-75% by weight. When the amount of organic solvent is too large, the resultant ink composition has no viscosity suitable for writing, and may not provide writing of a sufficient darkness. When the amount of the organic solvent is too small, the resultant ink composition has a viscosity too large to write well, and it is also bad in storage stability.

The ink composition of the invention may further contain a dialkyl ketone wherein the alkyl has 1-4 carbons such as methyl ethyl ketone or methyl isobutyl ketone, or a lower aliphatic carboxylic acid ester wherein the carboxylic acid has 2-4 carbons and the alkyl has 1-3 carbons preferably such as ethyl acetate or butyl acetate, as a dissolving aid for a resin in an organic solvent used which will be described hereinafter.

The ink composition of the invention contains a pigment as a colorant. The amount of the pigment is determined in accordance with the pigment used and the darkness required. However, when the amount is too large, the resultant ink composition may have too large a viscosity and may be poor in writability and storability as well as erasability of writing, while when the amount is too small, the resultant ink composition may provide infeaibly faint writing, and may also writing poor in erasability. Usually the ink composition of the invention contain a pigment in an amount of 1-30% by weight, preferably of 3-15% by weight.

A resin is contained in the ink composition so that the ink composition has a viscosity suitable for writing and has a suitable adhesion onto an impervious writing surface. It is necessary that the resin is soluble in the organic solvent used in the ink composition, and such a resin includes, for example, polyvinyl butyral resin, acrylic resin, styrene-acrylic copolymer resin, styrene-maleic acid copolymer resin, shellac resin and rosin-maleic acid copolymer resin.

When the resin is contained in excess, the resultant ink compositions may have too large a viscosity and may deteriorate in writability, storability and erasability of writing, whereas when the amount is too small, the resultant ink composition may not have a viscosity suitable for writing, and may also provide writing of insufficient erasability. Usually the ink compostion of the invention contains a resin in an amount of 1-20% by weight, preferably of 5-15% by weight.

The ink compostion of the invention contains a polyoxyethylene polyoxypropylene monoalkyl ether which is liquid at normal temperatures, and which preferably has an oxyethylene content of not more than 40% by weight, as a separating agent.

The polyoxyethylene polyoxypropylene monoalkyl ether used in the invention is commercially available, and may be exemplified by Nikkol PBC-31 or PBC-41 (Nikko Chemicals K.K., Japan), Newpol 50HB-55, 50HB-100, 50HB-260, 50HB-400, 50HB-600 or 50HB-1000 (Sanyo Kasei Kogyo K.K., Japan), Dovanox DL-0206, DM-2007 or DH-0300 (Lion K.K., Japan), Lionol L-358, L-745, L-785 or L-950 (Lion K.K., Japan).

The polyoxyethylene polyoxypropylene monoalkyl ether is contained in the ink composition in an amount of 5-20% by weight. When the amount of the polyoxyethylene polyoxypropylene monoalkyl ether is too small, the resultant ink composition may not have a sufficient erasability, whereas when the amount is too large, the resultant ink composition may have a viscosity too large for writing well, or write faintly. In particular, it is preferred that the ink composition contains the polyoxyethylene polyoxypropylene monoalkyl ether in an amount of 7-15% by weight.

The ink composition of the invention may contain a further separating agent or a second separating agent in conjunction with the above mentioned polyoxyethylene polyoxypropylene monoalkyl ether as a first separating agent.

The second separating agent is at least one organic compound selected from the group consisting of a carboxylic acid ester and a polyoxypropylene monoalkyl ether which is liquid at normal temperatures. The carboxylic acid ester may be a carboxylic acid alkyl ester, a dibasic acid diester or a mono- or polyester of a polydric alcohol.

Thus, there is provided in accordance with the invention, a further erasable ink composition for writing on an impervious writing surface comprising an organic solvent, a resin, a pigment, and a separating agent which comprises:

(a) a polyoxyethylene polyoxypropylene monoalkyl ether which is liquid at normal temperatures in an amount of 5-20% by weight; and

(b) at least one organic compound selected from the group consisting of a carboxylic acid ester and a polyoxypropylene monoalkyl ether which is liquid at normal temperatures in an amount of 2-10% by weight.

The carboxylic acid alkyl ester is preferably such a carboxylic acid alkyl ester wherein the carboxylic acid is a saturated or an unsaturated and has 8-20 carbons, and the alkyl has 2-20 carbons. Such a carboxylic acid alkyl ester may be exemplified by cetyl octanoate, isocetyl octanoate, stearyl octanoate, hexyl laurate, isostearyl laurate, butyl myristate, isopropyl palmitate, isostearyl palmitate, isopropyl isostearate, butyl isostearate, hexyl isostearate, isocetyl isostearate, ethyl oleate or decyl oleate.

The dibasic acid diester used includes an aliphatic dibasic carboxylic acid diester or an aromatic dibasic carboxylic acid diester, preferably a dialkyl ester wherein the alkyl has 2-20 carbons. Thus, the dibasic acid diester used includes, for instance, di-2-ethylhexyl succinate, diisopropyl adipate, dioctyl adipate, diisopropyl sebacate, dibutyl phthalate, dioctyl phthalate and diisodecyl phthalate.

The ester of polydric alcohol is preferably a mono-or a polyester derived from an aliphatic polyhydric alcohol of 4-8 carbons including glycols and a saturated or an unsaturated fatty acid of 6-24 carbons. Accordingly, the ester of polydric alcohol used includes, for instance, an ester of trimethylol propane such as trimethylol propane (mono, di or tri)oleate, trimethylol propane (mono, di or tri)caproate, tri-2-ethylhexyl trimethylates (such as trialkyl esters of trimethylol compound, exemplified by trimethylol propane), trimethylol propane triisopalmitate, trimethylol propane trioctanoate or trimethylol propane triisostearate; an ester of pentaerythritol such as pentaerythritol tetraoctanoate or pentaerythritol tetra-2-ethyl hexanoate; an ester of propylene glycol such as propylene glycol monocaprilate, propylene glycol dicaprilate or propylene glycol didecanoate; or a fatty acid (mono, di or tri)glyceride or a mixture of these (esters of glycerine and fatty acids) such as olive oil, safflower oil or coconut oil.

The polyoxypropylene monoalkyl ether is also commercially available, and may be exemplified by Newpol LB-65, LB-285, LB-385, LB-625, LB-1145, LB-1715 or LB-3000 (Sanyo Kasei Kogyo K.K., Japan).

The second separating agent is contained in the ink composition in an amount of 2-10% by weight, preferably of 3-8% by weight, based on the ink composition. When the amount of the second separating agent is too small, the resultant ink composition may not have a sufficient erasability, whereas when the amount is too large, the resultant ink composition may have a viscosity too large for writing well, or write faintly.

According to the invention, it is in particular preferred that the first and second separating agents are contained in conjunction in an amount of 10-23% by weight.

The ink composition of the invention may be produced by a conventional method, and is not limited to any specific method. By way of example, when a normal pigment is used as a colorant, the pigment is mixed with a resin in an organic solvent, the resultant mixture is milled in a beads mill to disperse the pigment finery in the solvent to form a mill base, there are added a separating agent and other components if necessary to the mill base, and then the resultant mixture is stirred. When a resin-coated pigment is used as a colorant, all the components may be mixed together at the same time, and the pigment may be dispersed in the solvent used with a paint shaker. In either methods, the resultant ink composition may be filtered or centrifuged to remove therefrom coarse materials.

Examples of the ink composition of the invention will now be described, however, the invention is not limited thereto. In the examples, parts are parts by weight.

    ______________________________________                                         Example 1                                                                      ______________________________________                                         Nikkol PBC-31           8 parts                                                Isocetyl isostearate    8 parts                                                Fuji AS Green.sup.1)    10 parts                                               Fuji AS White.sup.2)    3 parts                                                Ethyl alcohol           61 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                    

    ______________________________________                                         Example 2                                                                      ______________________________________                                         Newpol 50HB-100         5 parts                                                Isopropyl isostearate   12 parts                                               Fuji AS Blue.sup.3)     10 parts                                               Fuji AS White.sup.2)    3 parts                                                Ethyl alcohol           60 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                    

    ______________________________________                                         Example 3                                                                      ______________________________________                                         Newpol 50HB-260         12 parts                                               Butyl isostearate       4 parts                                                Fuji AS Red.sup.4)      10 parts                                               Fuji AS White.sup.2)    4 parts                                                Ethyl alcohol           51 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                    

    ______________________________________                                         Example 4                                                                      ______________________________________                                         Dovanox DL-0206         10 parts                                               Stearyl octanoate       5 parts                                                Fuji AS Orange.sup.5)   15 parts                                               Ethyl alcohol           60 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                    

    ______________________________________                                         Example 5                                                                      ______________________________________                                         Lionol L-358            7 parts                                                Butyl myristate         3 parts                                                Fuji AS White.sup.2)    20 parts                                               Ethyl alcohol           60 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                    

    ______________________________________                                         Reference Example 1                                                            ______________________________________                                         Stearyl octanoate       15 parts                                               Fuji AS Orange.sup.5)   13 parts                                               Fuji AS White.sup.2)    2 parts                                                Ethyl alcohol           60 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                    

    ______________________________________                                         Example 6                                                                      ______________________________________                                         Nikkol PBC-41           7 parts                                                Dioctyl adipate         8 parts                                                Fuji AS Orange.sup.5)   15 parts                                               Ethyl alcohol           60 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                    

    ______________________________________                                         Example 7                                                                      ______________________________________                                         Newpol 50HB-55          15 parts                                               Diisooctyl sebacate     8 parts                                                Fuji AS Green.sup.1)    10 parts                                               Fuji AS White.sup.2)    3 parts                                                Ethyl alcohol           51 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                    

    ______________________________________                                         Example 8                                                                      ______________________________________                                         Newpol 50HB-2000        5 parts                                                Dibutyl phthalate       6 parts                                                Fuji AS Blue.sup.3)     10 parts                                               Fuji AS White.sup.2)    3 parts                                                Ethyl alcohol           66 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                    

    ______________________________________                                         Example 9                                                                      ______________________________________                                         Dovanox DH-0300         8 parts                                                Dioctyl phthalate       4 parts                                                Fuji AS Red.sup.4)      10 parts                                               Fuji AS White.sup.2)    4 parts                                                Ethyl alcohol           64 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                    

    ______________________________________                                         Example 10                                                                     ______________________________________                                         Lionol L-358            7 parts                                                Diisodecyl phthalate    3 parts                                                Fuji AS White.sup.2)    20 parts                                               Ethyl alcohol           60 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                    

    ______________________________________                                         Reference Example 2                                                            ______________________________________                                         Dioctyl adipate         15 parts                                               Fuji AS Orange.sup.5)   15 parts                                               Ethyl alcohol           60 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                    

    ______________________________________                                         Example 11                                                                     ______________________________________                                         Newpol 50HB-400         8 parts                                                Trimethylol propane oleate                                                                             6 parts                                                Fuji AS Black.sup.6)    15 parts                                               Ethyl alcohol           61 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                    

    ______________________________________                                         Example 12                                                                     ______________________________________                                         Newpol 50HB-100         10 parts                                               Trimethylol propane     5 parts                                                trioctanoate                                                                   Fuji AS Orange.sup.5)   15 parts                                               Ethyl alcohol           60 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                    

    ______________________________________                                         Example 13                                                                     ______________________________________                                         Lionol L-745            8 parts                                                Pentaerythritol         6 parts                                                tetra-2-ethylhexanoate                                                         Fluorescent orange base 41 parts                                               White base              5 parts                                                Ethyl alcohol           35 parts                                               Isopropyl alcohol       5 parts                                                ______________________________________                                    

The above fluorescent orange base has the composition below:

    ______________________________________                                         Epocolor FP-40.sup.7)   36 parts                                               Denka Butyral.sup.9)    9 parts                                                Isopropyl alcohol       10 parts                                               Ethyl alcohol           45 parts                                               ______________________________________                                    

Such a pigment base as above may be usually prepared by adding a pigment to a solution of a resin such as polyvinyl butyral resin in an organic solvent, and mixing the resultant mixture in a bead mill.

The above white base has the composition below:

    ______________________________________                                         Titanium KR-380.sup.8)  60 parts                                               Denka Butyral.sup.9)    6 parts                                                Isopropyl alcohol       7 parts                                                Ethyl alcohol           27 parts                                               ______________________________________                                    

    ______________________________________                                         Example 14                                                                     ______________________________________                                         Newpol 50HB-55          12 parts                                               Olive oil.sup.12)       3 parts                                                Blue base               40 parts                                               White base              5 parts                                                Ethyl alcohol           35 parts                                               Propylene glycol monomethyl ether                                                                      5 parts                                                ______________________________________                                    

The above blue base has the composition below:

    ______________________________________                                         Phthlocyanine blue (dye)                                                                               13 parts                                               Esreck BL-1.sup.10)     13 parts                                               Solmix AP-1.sup.11)     74 parts                                               ______________________________________                                    

    ______________________________________                                         Reference Example 3                                                            ______________________________________                                         Pentaerythritol         14 parts                                               tetra-2-ethylhexanoate                                                         Fluorescent orange base 41 parts                                               White base              5 parts                                                Ethyl alcohol           35 parts                                               Isopropyl alcohol       5 parts                                                ______________________________________                                    

    ______________________________________                                         Example 15                                                                     ______________________________________                                         Nikkol PBC-31           15 parts                                               Fuji AS Orange.sup.5)   15 parts                                               Ethyl alcohol           60 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                    

    ______________________________________                                         Example 16                                                                     ______________________________________                                         Newpol 50HB-260         17 parts                                               Fuji AS Green.sup.1)    10 parts                                               Fuji AS White.sup.2)    3 parts                                                Ethyl alcohol           51 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                    

    ______________________________________                                         Example 17                                                                     ______________________________________                                         Dovanox DL-0206         11 parts                                               Fuji AS Blue.sup.3)     10 parts                                               Fuji AS White.sup.2)    3 parts                                                Ethyl alcohol           66 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                    

    ______________________________________                                         Example 18                                                                     ______________________________________                                         Lionol L-745            12 parts                                               Fuji AS Red.sup.4)      10 parts                                               Fuji AS White.sup.2)    4 parts                                                Ethyl alcohol           64 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                    

    ______________________________________                                         Example 19                                                                     ______________________________________                                         Newpol 50HB-660         8 parts                                                Fuji AS White.sup.2)    20 parts                                               Ethyl alcohol           62 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                    

    ______________________________________                                         Example 20                                                                     ______________________________________                                         Newpol 50HB-660         5 parts                                                Fluorescent orange base 41 parts                                               White base              5 parts                                                Ethyl alcohol           39 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                    

    ______________________________________                                         Example 21                                                                     ______________________________________                                         Nikkol PBC-31           8 parts                                                Newpol LB-65            6 parts                                                Fuji AS White.sup.2)    20 parts                                               Ethyl alcohol           56 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                    

    ______________________________________                                         Example 22                                                                     ______________________________________                                         Lionol L-950            10 parts                                               Newpol LB-285           5 parts                                                Fuji AS Orange.sup.5)   15 parts                                               Ethyl alcohol           60 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                    

    ______________________________________                                         Reference Example 4                                                            ______________________________________                                         Newpol LB-285           15 parts                                               Fuji AS Orange.sup.5)   15 parts                                               Ethyl alcohol           60 parts                                               Isopropyl alcohol       10 parts                                               ______________________________________                                          Notes:                                                                         .sup.1)-6) Polyvinyl butyral resincoated pigment dispersible in alcohols,      available from Fuji Shikiso K.K., Japan                                        .sup.7) Fluorescent orange pigment available from Nihon Shokubai Kogyo         K.K. Japan                                                                     .sup.8) Titanium dioxide available from Titan Kogyo K.K., Japan                .sup.9) Polyvinyl butyral resin available from Denki Kagaku Kogyo K.K.,        Japan                                                                          .sup.10) Polyvinyl butyral resin available from Sekisui Kagaku Kogyo K.K.      Japan                                                                          .sup.11) Modified ethanol available from Nippon Kasei K.K., Japan              .sup.12) Available from Nikko Chemicals K.K., Japan                      

Writing was formed on various impervious writing surfaces as shown in Table 1, and its initial erasability and standing erasability were examined. The initial erasability is defined as the erasability of writing when being wiped with an eraser made of felt immediately after the writing was formed, and the standing erasability is defined as the erasability of writing when being wiped with an eraser made of felt after standing at a temperature of 40° C. and a relative humidity of 40% for seven days. Among the writing boards, there were used two melamine resin boards.

The erasability was evaluated as follows. When the writing was erased by wiping five times with a sheet of felt (5 cm×5 cm) under a load of 200 g or 400 g, the erasability was marked "A"; when the writing was erased by wiping eight times under a load of 800 g, the erasability was marked "B"; and when the writing was not erased by wiping ten times under a load of 800 g, the erasability was marked "C". The mark "-" indicates that evaluation is not possible since the color of the writing board was the same as that of the writing formed thereon.

As indicated in Table 1, the ink composition of the invention provides writing on an impervious surface which is readily erasable after long standing. The ink composition has also erasability substantially independent on the material of impervious surface, and provide erasable writing on any impervious surface.

More specifically, the ink composition of the invention contains the polyoxyethylene polyoxypropylene monoalkyl ether as the first separting agent which improves, in particular, erasability of writing after long standing. The use of the second separting agent in conjunction with the first separating agent further improves the erasability of writing after long standing. The carboxylic acid ester is especially useful in this connection. In turn, the polyoxypropylene monoalkyl ether is less effective in initial erasability of writing than the carboxylic acid ester, however, it is more effective to improve erasability of writing after long standing. Moreover, the use of the first and second separating agent in conjunction improves coloration of ink composition on a dark color writing board such as of dark green.

                                      TABLE 1                                      __________________________________________________________________________             Melamine,                                                                               Melamine,                                                                               Acrylic,  Melamine,                                                                               Enameled,                                                                               Polyester,                       Black Board A                                                                           Black Board B                                                                           Transparent Board                                                                        White Board                                                                             White Board                                                                             White Board                      Initial                                                                            Standing                                                                            Initial                                                                            Standing                                                                            Initial                                                                             Standing                                                                            Initial                                                                            Standing                                                                            Initial                                                                            Standing                                                                            Initial                                                                            Standing             __________________________________________________________________________     Example                                                                              1 A   B    A   B    A    B    A   B    A   A    A   B                          2 A   A    A   A    A    A    A   A    A   A    A   B                          3 A   A    A   A    A    A    A   A    A   A    A   A                          4 A   B    B   B    A    B    A   B    A   A    B   B                          5 A   B    A   B    A    B    --  --   --  --   --  --                   Reference                                                                            1 A   C    B   C    A    C    A   C    A   A    B   B                    Example 1                                                                      Example                                                                              6 A   B    A   A    A    A    A   A    A   A    B   B                          7 A   B    A   B    A    B    A   B    A   A    A   B                          8 B   A    A   A    A    A    A   A    A   A    A   B                          9 A   B    A   B    A    B    A   A    A   A    B   B                          10                                                                               A   A    A   B    A    A    --  --   --  --   --  --                   Reference                                                                            2 B   C    A   C    A    C    B   C    A   B    B   C                    Example 1                                                                      __________________________________________________________________________

                                      TABLE 2                                      __________________________________________________________________________             Melamine,                                                                               Melamine,                                                                               Acrylic,  Melamine,                                                                               Enameled,                                                                               Polyester,                       Black Board A                                                                           Black Board B                                                                           Transparent Board                                                                        White Board                                                                             White Board                                                                             White Board                      Initial                                                                            Standing                                                                            Initial                                                                            Standing                                                                            Initial                                                                             Standing                                                                            Initial                                                                            Standing                                                                            Initial                                                                            Standing                                                                            Initial                                                                            Standing             __________________________________________________________________________     Example                                                                              11                                                                               --  --   --  --   A    B    A   B    A   A    A   B                          12                                                                               A   A    A   A    A    B    A   B    A   A    A   B                          13                                                                               A   B    A   A    A    A    A   A    A   A    A   B                          14                                                                               A   B    A   B    A    B    A   A    A   A    A   B                    Reference                                                                             4                                                                               A   C    B   C    A    C    A   C    A   A    B   C                    Example 3                                                                      Example                                                                              15                                                                               A   B    A   B    A    A    A   A    A   A    A   B                          16                                                                               A   A    A   A    A    A    A   A    A   A    A   B                          17                                                                               A   B    A   B    A    A    A   A    A   A    A   B                          18                                                                               A   B    A   A    A    A    A   A    A   A    A   B                          19                                                                               A   B    A   A    A    A    --  --   --  --   --  --                         20                                                                               A   B    A   A    A    A    A   A    A   A    A   A                    Example                                                                              21                                                                               A   A    A   B    A    B    --  --   --  --   --  --                         22                                                                               A   A    A   A    A    B    A   B    A   A    B   B                    Reference                                                                             4                                                                               A   C    B   C    A    C    A   C    A   A    B   C                    Example 1                                                                      __________________________________________________________________________ 

What is claimed is:
 1. An erasable ink composition for writing on an impervious writing surface comprising:an organic solvent selected from the group consisting of an aliphatic alcohol of 1-4 carbons and a monoalkyl ether of a glycol of 2-4 carbons; a resin selected from the group consisting of polyvinyl butyral resin, acrylic resin, styrene-acrylic copolymer resin, styrene-maleic acid copolymer resin, shellac resin and rosin-maleic acid copolymer resin in an amount of 1-20% by weight; a pigment in an amount of 1-30% by weight; and a polyoxyethylene polyoxypropylene monoalkyl ether which is liquid at normal temperatures as a separating agent in an amount of 5-20% by weight.
 2. The ink composition as claimed in claim 1 wherein the organic solvent is ethyl alcohol or isopropyl alcohol, or a mixture of these.
 3. An erasable ink composition for writing on an impervious writing surface comprising:an organic solvent selected from the group consisting of an aliphatic alcohol of 1-4 carbons and a monoalkyl ether of a glycol of 2-4 carbons; a resin selected from the group consisting of polyvinyl butyral resin, acrylic resin, styrene-acrylic copolymer resin, styrene-maleic acid copolymer resin, shellac resin and rosin-maleic acid copolymer resin in an amount of 1-20% by weight; a pigment in an amount of 1-30% by weight; and a separating agent which comprises:(a) a polyoxyethylene polyoxypropylene monoalkyl ether which is liquid at normal temperatures as a first separating agent in an amount of 5-20% by weight; and (b) a carboxylic acid ester which is liquid at normal temperatures as a second separating agent in an amount of 2-10% by weight.
 4. The ink composition as claimed in claim 3 wherein the organic solvent is ethyl alcohol or isopropyl alcohol, or a mixture of these.
 5. The ink composition as claimed in claim 3 wherein the carboxylic acid ester is an alkyl ester of a saturated or an unsaturated carboxylic acid wherein the carboxylic acid has 8-20 carbons and the alkyl has 2-20 carbons.
 6. The ink composition as claimed in claim 3 wherein the carboxylic acid aster is an aliphatic dibasic carboxylic acid diester or an aromatic dibasic carboxylic acid diester wherein the alkyl has 20-20 carbons.
 7. The ink composition as claimed in claim 3 wherein the aliphatic dibasic carboxylic acid diester is a succinate, an adipate or a sebacate.
 8. The ink composition as claimed in claim 3 wherein the aromatic dibasic carboxylic acid diester is a phthalate.
 9. The ink composition as claimed in claim 3 wherein the carboxylic acid ester is an ester of an aliphatic polyhydric alcohol of 4-8 carbons and a saturated or an unsaturated fatty acid of 6-24 carbons.
 10. The ink composition as claimed in claim 9 wherein the polyhydric alcohol is glycerine, trimethylol propane, pentaerythritol or propylene glycol.
 11. The ink composition as claimed in claim 3 which contains the first and the second separating agents in conjunction in an amount of 10-23% by weight.
 12. The ink composition as claimed in claim 3 which further contains a dialkyl ketone wherein the alkyl has 1-4 carbons or a lower aliphatic carboxylic acid ester wherein the carboxylic acid has 2-4 carbons and the alkyl has 1-3 carbons.
 13. The ink composition as claimed in claim 3 wherein the resin is polyvinyl butyral.
 14. An erasable ink composition for writing on an impervious writing surface comprising:an organic solvent selected from the group consisting of an aliphatic alcohol of 1-4 carbons and a monoalkyl ether of a glycol of 2-4 carbons; a resin selected from the group consisting of polyvinyl butyral resin, acrylic resin, styrene-acrylic copolymer resin, styrene-maleic acid copolymer resin, shellac resin and rosin-maleic acid copolymer resin in an amount of 1-20% by weight; a pigment in an amount of 1-30% by weight; and a separating agent which comprises:(a) a polyoxyethylene polyoxypropylene monoalkyl ether which is liquid at normal temperatures as a first separating agent in an amount of 5-20% by weight; and (b) a polyoxypropylene monoalkyl ether which is liquid at normal temperatures as a second separating agent in an amount of 2-10% by weight.
 15. The ink composition as claimed in claim 14 wherein the organic solvent is ethyl alcohol or isopropyl alcohol, or a mixture of these.
 16. The ink composition as claimed in claim 14 which contains the first and the second separating agents in conjunction in an amount of 10-23% by weight.
 17. The ink composition as claimed in claim 14 which further contains a dialkyl ketone wherein the alkyl has 1-4 carbons or a lower aliphatic carboxylic acid ester wherein the carboxylic acid has 2-4 carbons and the alkyl has 1-3 carbons.
 18. The ink composition as claimed in claim 14 wherein the resin is polyvinyl butyral. 